Scientific Overview

Photonics, the science of generating and manipulating light, is a key technology of the 21st century; it has been identified by the European Investment Bank as being one of the “building blocks of the next digital revolution”. Photonics underpins all aspects of modern society, including optical telecommunications, biophotonics, medical devices, optical sensors and materials processing, with a global market expected to reach €615 billion by 2020 and growing. Photonic sensors are a key element of the sector; measurement of molecular-specific optical transitions allows qualitative and quantitative analysis in-situ, without the need to chemically prepare or damage the sample in question, and hence is hugely attractive for a wide range of applications, from Process Analytical Technology (PAT) to biomedical diagnostics.

Due to Europe’s strong activity in optical sensing and the large variety of applications, it is becoming increasingly difficult for all sectors to find highly skilled photonics graduates, particularly at the interfaces between sectors. In particular, optical sensing is intrinsically a multi-disciplinary topic, requiring expertise in chemistry, physics and engineering, making truly disruptive innovation difficult within a traditional Ph.D. project. The OPTAPHI network (pronounced opta-fy) aims to address this by training a cohort of doctoral students in the complementary fields of advanced spectroscopy and integrated optics. Specifically, the focus is on the methods of photo-acoustic and photo-thermal spectroscopy, and the compact semiconductor lasers and integration techniques that enable sensors based on these.

Photo-Acoustic and Photo-Thermal Spectroscopy

The absorption of light by a sample (gas, liquid, solid) causes the sample to heat up; if the pump light is modulated, this produces a sequence of gas heating and cooling, leading to the generation of thermal and acoustic (sound) waves. Quartz Enhanced Photo-Acoustic Spectroscopy (QEPAS) and Photo-Thermal Spectroscopy (PTS) are ultra-sensitive techniques based on the detection of these acoustic and thermal waves. In QEPAS, a quartz tuning fork is used to detect the acoustic waves created in a gas sample, and is immune to external acoustic noise. PTS detects the refractive index change caused by the absorption-induced heating, using a Fabry-Pérot interferometer. Both techniques can potentially detect extremely low concentrations, at parts per trillion levels or less. PTS can also be applied to liquid sensing and, in combination with Atomic Force Microscopy (AFM), to near-field IR imaging.

Semiconductor Lasers and Integrated Photonics

The gases which can be detected by QEPAS and PTS depend on the pump laser used, the wavelength of which must be tailored to the absorption lines of the target gas. In order to realise compact, portable and low-cost sensors, these lasers need to have the small footprint of semiconductor lasers, similar to those used in e.g. the telecoms industry, and be closely integrated with the QEPAS/PTS cell. OPTAPHI will develop new hybrid photonic crystal lasers, long wavelength quantum cascade lasers, and III-V lasers grown on silicon, with new wavelength locking mechanisms and analysis techniques, to greatly reduce system size and improve robustness of the optical sensors. Regarding near-field IR imaging it will also conceive new transducers for simultaneously detecting thermal and chemical properties of solid samples with nanometre resolution.

OPTAPHI Scientific Objectives

  • Demonstrate novel Quartz Enhanced Photo-Acoustic Spectroscopy (QEPAS) and Photo-Thermal Spectroscopy (PTS) configurations with improved sensitivity and compactness
  • Demonstrate improved detection of benzene, toluene, ethylbenzene and xylene (BTEX) and propane exploiting long wavelength 10+ μm laser sources
  • Demonstrate highly sensitive Photo-Thermal Spectroscopy for liquid analysis for the first time
  • Improve the compactness, robustness and power consumption of QEPAS to allow use on Unmanned Aerial Vehicles
  • Demonstrate new methodologies to improve the sensitivity of PTS and QEPAS in the second overtone band, thereby allowing the use of low-cost telecoms components

The research activities in OPTAPHI are grouped into 3 Work Packages, addressing different application areas, but utilising similar cross-cutting technology.

Click on the WP title for more details.

WP1: Environmental Sensing

WP2: Agri-Food Analysis

WP3: Industrial Process Monitoring

Research Skills Addressed

Refer to the Projects page for more details on individual projects.